New ionic half-metallocenes of early lanthanides
نویسندگان
چکیده
منابع مشابه
New ionic half-metallocenes of early lanthanides
We present in this study a new and one-step method allowing the preparation of an unprecedented family of stable half-lanthanidocenes. X Ray analysis shows that the isolated compounds all display the same ionic Ln-Mg bimetallic structure consisting of two anionic (Cp)Ln(BH4)3 species and one cationic Mg(THF)6 (Cp = C5Me5, Ln = Nd, 1a, Ln = La, 1b; Cp = C5H5, Ln = Nd, 2a; Cp = C5H2Ph3, Ln = Nd, ...
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ژورنال
عنوان ژورنال: Journal of Alloys and Compounds
سال: 2008
ISSN: 0925-8388
DOI: 10.1016/j.jallcom.2007.04.140